Hexa-μ2-acetato-hexa-n-butylhexa-μ3-oxido-tin(IV) toluene monosolvate
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چکیده
منابع مشابه
Hexa-μ2-acetato-hexa-n-butylhexa-μ3-oxido-tin(IV) toluene monosolvate
The title compound, [Sn6(C4H9)6(CH3COO)6O6]·C7H8, has one half-toluene mol-ecule and one half-organotin mol-ecule in the asymmetric unit. The latter is situated about an inversion centre and belongs to the class of hexa-meric monoorganooxo-tin carboxyl-ates with a hexa-gonal prismatic or 'drum-like' motif of the central tin-oxygen core. Two Sn3O3 rings in a flat-chair conformation are linked vi...
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The title compound, (C(6)H(16)N)[Fe(3)(CH(3)CO(2))(8)O(H(2)O)]·C(7)H(8), was serendipitously crystallized from a reaction of disilanol with iron(II) acetate. The trinuclear acetatoferrate(III) anion has a triethyl-ammonium cation as the counterion. The three Fe atoms lie on the vertices of a regular triangle and are octa-hedrally coordinated. The complete coordination of the anion includes shar...
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In the crystal structure of the title complex, [Cr(3)(CH(3)CO(2))(6)(N(3))O(CH(3)OH)(2)]·CH(3)OH, the trinuclear core has a central O atom; two methanol mol-ecules and an azide ion are coordinated to the Cr(III) atoms in the core. The three Cr(III) atoms form vertices of a nearly equilateral triangle. Each of the six acetate carboxyl-ate groups bridges a Cr-O-Cr fragment. In the crystal, the mo...
متن کاملHexa-μ2-acetato-triaqua-μ3-oxido-triiron(III) nitrate acetic acid solvate
The asymmetric unit of the title compound, [Fe(3)(CH(3)COO)(6)O(H(2)O)(3)]NO(3)·CH(3)COOH, consists of a hexa-μ(2)-acetato-triaqua-μ(3)-oxo-triiron(III) macrocation, a nitrate ion and an acetic acid solvent mol-ecule. In the cation, each Fe(3+) ion is coordinated by four carboxyl-ate O atoms, one central bridged O atom and one water mol-ecule, resulting in distorted FeO(6) octa-hedra. A network...
متن کاملHexa-μ2-acetato-κ12 O:O′-μ3-oxido-tris[aquachromium(III)] nitrate acetic acid solvate
In the crystal structure of the title salt, [Cr(3)(C(2)H(3)O(2))(6)O(H(2)O)(3)]NO(3)·CH(3)CO(2)H, the trinuclear [Cr(3)(CH(3)CO(2))(6)O(H(2)O)(3)] cluster cation has an oxide O atom that is connected to three water-coordinated Cr(III) atoms, the three metal atoms forming the points of an equilateral triangle. Each of the six acetate carboxyl-ate groups bridges a Cr-O-Cr fragment. The cluster ca...
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ژورنال
عنوان ژورنال: Acta Crystallographica Section E Structure Reports Online
سال: 2012
ISSN: 1600-5368
DOI: 10.1107/s160053681204888x